Catalytic oxidation of cyclohexane to cyclohexanone and cyclohexanol by tert-butyl hydroperoxide over Pt/oxide catalysts
نویسندگان
چکیده
منابع مشابه
Selective catalytic oxidation of organosulfur compounds with tert-butyl hydroperoxide.
Rates and selectivities for the oxidation of various organosulfur compounds with tert-butyl hydroperoxide were measured on CoAPO-5 (APO = aluminophosphate; Co/P = 0.05), Co/H-Y (Co/Al = 0.15), and MoO(x)/Al2O3 (15 % wt MoO3). Rates increased with increasing electron density at the sulfur atom (methyl phenyl sulfide>diphenyl sulfide>4-methyldibenzothiophene>2,5-dimethyl thiophene). Rates (per me...
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In the present work, highly efficient oxidation of sulfides catalyzed by MoO2(acac)2 supported on multi-wall carbon nanotubes, MWCNTs, modified with 1,2-diaminobenzene (DAB) and 2-aminophenol (AP), at room temperature are reported. The effects of various parameters such as reaction time, solvent, catalyst amount, oxidant, etc, were studied. These heterogenized catalysts showed high activity in ...
متن کاملSelective Oxidation of Cyclohexane to Cyclohexanone
Cyclohexane oxidation is an important commercial reaction for the preparation of cyclohexanol and cyclohexanone, which are intermediates in the production of adipic acid and caprolactam respectively. These intermediates are important in the manufacture of nylon-6 and nylon-6,6 polymers (Yuan et al 2006 and Shylesh et al 2007). In addition, cyclohexanol and cyclohexanone are also used as solvent...
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in the present work, highly efficient oxidation of sulfides catalyzed by moo2(acac)2 supported on multi-wall carbon nanotubes, mwcnts, modified with 1,2-diaminobenzene (dab) and 2-aminophenol (ap), at room temperature are reported. the effects of various parameters such as reaction time, solvent, catalyst amount, oxidant, etc, were studied. these heterogenized catalysts showed high activity in ...
متن کاملmulti-wall carbon nanotubes supported molybdenum acetylacetonate: efficient and highly reusable catalysts for oxidation of sulfides with tert-butyl hydroperoxide
in the present work, highly efficient oxidation of sulfides catalyzed by moo2(acac)2 supported on multi-wall carbon nanotubes, mwcnts, modified with 1,2-diaminobenzene (dab) and 2-aminophenol (ap), at room temperature are reported. the effects of various parameters such as reaction time, solvent, catalyst amount, oxidant, etc, were studied. these heterogenized catalysts showed high activity in ...
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ژورنال
عنوان ژورنال: Bulletin of Materials Science
سال: 2011
ISSN: 0250-4707,0973-7669
DOI: 10.1007/s12034-011-0157-6